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Dissolved and particulate concentrations of the biogenic thiols cysteine (Cys), arginine–cysteine (Arg–Cys), glutamine–cysteine (Gln–Cys), γ-glutamate–cysteine (γ-Glu–Cys) and glutathione (GSH) were measured in the subartic Pacific Ocean in the summer of 2003 using high performance liquid chromatography (HPLC) with precolumn derivatization as reported in previous work. In this study, a preconcentration protocol for the derivatized thiols was utilized to extend detection limits of dissolved thiols to picomolar levels. The measured concentrations of particulate and dissolved thiols were uncoupled, with distinctive depth profiles and large differences in the particulate to dissolved ratios between individual compounds. Glutathione was the most abundant particulate thiol whereas the most abundant dissolved thiol was γ-Glu–Cys, with concentrations as high as 15 nM. Given the relatively small pool of intracellular γ-Glu–Cys and the very low dissolved concentrations of GSH, we hypothesize that glutathione released from cells is rapidly converted to the potentially degradation resistant γ-Glu–Cys outside the cell. The relatively high concentrations of other dissolved thiols compared to particulate concentrations implies both biological exudation and slow degradation rates. Some thiols appear to vary with changes in nutrient availability but this effect is difficult to decouple from changes in community structure inferred from pigment analyses. Dissolved thiol concentrations also exceed typical metal concentrations in the subartic Pacific, supporting previous arguments that they may be important in metal speciation.  相似文献   
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In this paper we discuss the results of a swath bathymetric investigation of the Canary archipelago offshore area. These new data indicate that volcanism is pervasive throughout the seafloor in the region, much more that would be suggested by the islands. We have mapped tens of volcanic edifices between Fuerteventura and Gran Canaria and offshore Tenerife, La Gomera, El Hierro and La Palma. Volcanic flows are present between Tenerife and La Gomera and salic necks dominate the eastern insular slope of La Gomera. This bathymetry also supports land geologic studies that indicate that the oceanic archipelago has acquired its present morphology in part by mass wasting, a consequence of the collapse of the volcanic edifices. In the younger islands, Tenerife, La Palma and El Hierro, the Quaternary (1.2 to 0.15 Ma) debris avalanches are readily recognizable and can be traced offshore for distances measured in tens of km. Off the older islands, Lanzarote, Fuerteventura, Gran Canaria and La Gomera (<20 to 3.5 Ma), the avalanches have been obscured by subsequent turbidity current deposition and erosion as well as hemipelagic processes. The failure offshore western Lanzarote is in the form of a ramp at the base of the insular slope bound on the seaward side by a scarp. Its size and the lack of evidence of rotation along its landwards side precludes the possibility that it is a slump. It probably represents a slide whose outer scarp is caused by break-up of the slide. Mounds on the ramp’s surface may represent post-displacement volcanic structures or exotic blocks transported to their present locations by the slide. The failures offshore Fuerteventura are so large that, although they occurred in the Miocene-Pliocene, exotic blocks displaced from upslope are still recognizable in the insular margin morphology. The Canary Island insular margin appears to be a creation of Miocene-Pliocene mass wasting and more recent turbidity current deposition and erosion, and hemilepagic deposition. Failures offshore La Gomera are due to debris flows and/or turbidity currents. These events have obscured earlier mass wasting events. An erratum to this article is available at .  相似文献   
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Recent electrochemical measurements have shown that iron (Fe) speciation in seawater is dominated by complexation with strong organic ligands throughout the water column and have provided important thermodynamic information about these compounds. Independent work has shown that iron exists in both soluble and colloidal fractions in the Atlantic Ocean. Here we have combined these approaches in samples collected from a variety of regimes within the Atlantic Ocean. We measured the partitioning of Fe between soluble (< 0.02 μm) and colloidal (0.02 to 0.4 μm) size classes and characterized the concentrations and conditional stability constants of Fe ligands within these size classes. Results suggest that equilibrium partitioning of Fe between soluble and colloidal ligands is partially responsible for the distribution of Fe between soluble and colloidal size classes. However, a significant fraction of the colloidal Fe was inert to ligand exchange as soluble Fe concentrations were generally lower than values predicted by a simple equilibrium partitioning model.In surface waters, strong ligands with conditional stability constants of 1013 relative to total inorganic Fe appeared to dominate speciation in both the soluble and colloidal fractions. In deep waters these ligands were absent, and instead we found ligands with stability constants 12–15 fold smaller that were predominantly in the soluble pool. Nevertheless, significant levels of colloidal Fe were found in these samples, which we inferred must be inert to coordination exchange.  相似文献   
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An analytical model is proposed for predicting the dynamics of instrumented oceanographic surface moorings made up of a combination of wire rope and compliant synthetic rope. The model simplifies the problem by treating only the vertical motion of the buoy and the longitudinal motion of the mooring line and attached instruments. It is demonstrated using full-scale experimental data and numerical simulations, that the simplified model captures all of the important dynamic effects and gives accurate predictions of the dynamic tension at the top of the mooring line. The model shows that the total mass and damping of the instruments and wire rope that make up the stiff upper half of the mooring are the major sources of the dynamic tension. Damping of the instruments becomes a significant factor in larger sea states, especially near the peak frequency of the wave spectrum. Elastic stretching of the wire and synthetic rope make up approximately 10% of the total response. This is based on a coefficient of friction equal to 0.003 which fits the experimental data best.  相似文献   
38.
The role of relative sea-level rise as a cause for the rapid erosion of Louisiana's barrier island coast is investigated through a numerical implementation of a modified Bruun rule that accounts for the low percentage of sand-sized sediment in the eroding Louisiana shoreface. Shore-normal profiles from 150 km of coastline west of the Mississippi delta are derived from bathymetric surveys conducted during the 1880s, 1930s and 1980s. An RMS difference criterion is employed to test whether an equilibrium profile form is maintained between survey years. Only about half the studied profiles meet the equilibrium criterion; this represents a significant limitation on the potential applicability of the Bruun rule. The profiles meeting the equilibrium criterion, along with measured rates of relative sea-level rise, are used to hindcast shoreline retreat rates at 37 locations within the study area. Modeled and observed shoreline retreat rates show no significant correlation. Thus, in terms of the Bruun approach, relative sea-level rise has no power for hindcasting (and presumably forecasting) rates of coastal erosion for the Louisiana barrier islands.  相似文献   
39.
SeaMARC side-scan sonographs and Argo video and photographic data suggest that the recent sedimentary environment of the floor of the Tongue of the Ocean is controlled by an interplay of turbidity current flow from the south, sediment spill-over from the carbonate platform to the east (windward side), and rock falls from the west carbonate escarpment (lee side). The spill-over forms a sandy sedimentary deposit that acts as a topographic obstruction to the turbidity current flow from the south. This obstruction is expressed by the westward migration of a northwest-southeast oriented turbidity-current-cut channel.  相似文献   
40.
Observations of the Labrador Sea eddy field   总被引:2,自引:0,他引:2  
This paper is an observational study of small-scale coherent eddies in the Labrador Sea, a region of dense water formation thought to be of considerable importance to the North Atlantic overturning circulation. Numerical studies of deep convection emphasize coherent eddies as a mechanism for the lateral transport of heat, yet their small size has hindered observational progress. A large part of this paper is therefore devoted to developing new methods for identifying and describing coherent eddies in two observational platforms, current meter moorings and satellite altimetry. Details of the current and water mass structure of individual eddy events, as they are swept past by an advecting flow, can then be extracted from the mooring data. A transition is seen during mid-1997, with long-lived boundary current eddies dominating the central Labrador Sea year-round after this time, and convectively formed eddies similar to those seen in deep convection modeling studies apparent prior to this time. The TOPEX / Poseidon altimeter covers the Labrador Sea with a loose “net” of observations, through which coherent eddies can seem to appear and disappear. By concentrating on locating and describing anomalous events in individual altimeter tracks, a portrait of the spatial and temporal variability of the underlying eddy field can be constructed. The altimeter results reveal an annual “pulsation” of energy and of coherent eddies originating during the late fall at a particular location in the boundary current, pinpointing the time and place of the boundary current-type eddy formation. The interannual variability seen at the mooring is reproduced, but the mooring site is found to be within a localized region of greatly enhanced eddy activity. Notably lacking in both the annual cycle and interannual variability is a clear relationship between the eddies or eddy energy and the intensity of wintertime cooling. These eddy observations, as well as hydrographic evidence, suggest an active role for boundary current dynamics in shaping the energetics and water mass properties of the interior region.  相似文献   
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